Snow precipitator

ABSTRACT

In a snow-making machine which includes a tunnel-like housing, ice nuclei are generated by homogeneous nucleation in a separate zone or part of the air stream within the housing by injecting propane or other refrigerants into a stream of moist air. A propeller at one end of the tunnel moves an air mass through the tunnel carrying the ice nuclei with it. Water slightly above its freezing temperature is discharged through a nozzle disposed in the tunnel and is broken up into droplets. The droplets are discharged in a direction countercurrent to the flow of the air mass and ice nuclei. The air mass supercools the droplets, and they are then infected with the ice nuclei. The ice-infected droplets are then dispersed through a large volume of air to effect the removal of latent heat from the drops to form snowlike particles.

United States Patent Eustls et al.

[54] SNOW PRECIPITATOR [72] inventors: William E. C. Emtls, Cambridge; Wallace E. Howell, Lexington, both of Mass.

[73] Assignee: Hedco, lnc., Bedford, Mass. [22] Filed: July 23, 1971 21 Appl. No.: 165,688

Related us. Application Data [63] Continuation of Ser. No. 854,103, Aug. 29,

I969, abandoned.

[52] US. Cl ..239/2 S 51 Int. Cl ..A0lg 15/00, EOlh 13/00 [58] Field of Search ..239/2 S, 14, 399

[56] 7 References Cited UNITED STATES PATENTS 2,968,164 1/1961 Hanson ..239/2 S 2,571,069 10/1951 Shearman ..239/14 X 2,676,471 4/1954 Pierce, Jr ..239/2 S 3,010,660 11/1961 Barrett ..239/14 3,127,107 3/1964 Merryweather ..239/2 S 3,146,951 9/1964 Brown ..239/399 3,257,815 6/1966 Brocoff et al ..239/2 S A I R PROPANE 51 Nov. 28, 1972 3,272,434 9/1966 Zettlemeyer et al ..239/2 S 3,298,612 l/ 1967 Torrens ..239/ 14 X FOREIGN PATENTS OR APPLICATIONS 1,372,024 8/ 1964 France ..239/2 '8 Primary ExaminerLloyd LLKing AttomeyRichard P. Crowley and Richard L. Stevens [57] ABSTRACT In a snow-making machine which includes a tunnellike housing, ice nuclei are generated by homogeneous nucleation in a separate zone or part of the air stream within the housing by injecting propane or other refrigerants into a stream of moist air, A propeller at one end of the tunnel moves an air mass through the tunnel carrying the ice nuclei with it. Water slightly above its freezing temperature is discharged through a nozzle disposed in the tunnel and is broken up into droplets. The droplets are discharged in a direction counter-current to the flow of the air mass and ice nuclei. The air mass supercools the droplets, and they are then infected with the ice nuclei. The ice-infected droplets are then dispersed through a large volume of air to efl'ect the removal of latent heat from the drops to form snow-like particles.

14 Claims, 3 Drawing Figures 11 IIIIIIII ICE NUCLEI lI/l/l/I/l/l/I/I/Al/ WATER SNOW PRECIPITATOR CROSS-REFERENCE TO RELATED APPLICATION SUMMARY OF THE INVENTION The purpose of a snow-making apparatus is to emit at least partially frozen particles which will gather on the ground as a more or less loose snow-like mass suitable for skiing. An essential property of any snow-making device is that it effects the initiation of the freezing process in a large proportion of the water particles generated, otherwise the spray produces an artificial ice storm.

In the state of the art today, the proper role of nucleation as the necessary initiation of freezing has not generally been recognized or clearly identified. The prior art in at least one instance discloses combining compressed air and pressurized water in a helically moving chamber and discharging the mixture through a nozzle. Upon discharge, the mixture forms ice crystals. (See US. Pat. No. 3,301,485). Also a mixture of water and crushed ice discharged through a nozzle into an ambient stream of air at less than C to precipitate snow crystals has been suggested. (See US. Pat. No. 2,968,164).

The primary drawbacks of the present methods and apparatus for snow making are that the nucleating portion of the snow-making process and the crystallization of the water droplets in the air stream have been performed substantially simultaneously or more or less accidentally by unrecognized brute force, without regard to controlling the sets of parameters which affect each step in the process. This results in uneconomical and inefficient apparatus for making snow, with the attendant high cost.

To form frozen particles more is required than simply the cooling of the water to a temperature below 0C in the course of its emission and subsequent fall, for water when it is cooled below 0C does not start to freeze until a nucleus of the frozen phase appears. This nucleus may arise through collision between the cooling water particles and a bit of natural ice (isomorphic nucleation), or through the action of a foreign particle of some other substance, the crystalline, molecular or other structure of which somewhat resembles ice or otherwise effects the onset of the ice phase (heterogeneous nucleation), or through cooling of the liquid phase to such a low temperature that the ice phase appears spontaneously without the introduction of any foreign matter (homogeneous nucleation), which in water at atmospheric pressure occurs at about 40C. Unless the onset of freezing is initiated in one of these three ways, the water particle below 0C remains in a supercooled state until it strikes the ground, where it freezes in the form of glaze or ice, generally too hard for skiing and too rough for skating.

In our invention, the production of ice nuclei is separated from the function of disintegrating the water stream and of cooling the resulting water droplets and is accomplished by cooling of moist air below the temperature of homogeneous nucleation in a separate zone, either by adiabatic expansion of moist compressed air in an efficient nozzle, or by injection into moist cold air of a refrigerant, such as liquid propane,

or both; and the zone is so designed as to pemiit ice nuclei to grow to such a size that they may survive the few fractions of a second during which they are to become mixed with the droplet spray.

Likewise, the zone in which the droplet spray is generated is so designed that the bulk water may be brought to a temperature just barely above 0C before leaving a nozzle and may be mixed with a stream of cold air and so be brought to a supercooled state within I a very short distance after leaving the nozzle. After each separate step has been accomplished, mixture of the drop spray with the nucleus cloud is then effectuated. Finally, the spray is mixed with a rapidly moving air stream propelled from a blower in such a way as to spread it through a large volume of the atmosphere, 7

with which it exchanges latent heat during the freezing of the drops. The ice crystals then formed fall to the ground as more or less completely frozen snow-like particles.

Accordingly, in our invention the individual steps required for making snow are each controlled to ensure economic and efficient results.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic and partially sectional view of our snow precipitator; and

FIG. 2 is an alternative embodiment of our invention; and' FIG. 3 is a further alternative embodiment of our nucleating chamber.

DESCRIPTION OF THE PREFERRED EMBODIMENT Referring to FIG. 1, the snow precipitator is shown generally at 10 and includes a housing or tunnel-like conduit 12 together with a propeller or fan 14 secured to the housing by a bracket 16, to move air through the housing and carry the ice crystals into the atmosphere. Disposed in the downstream gr high pressure side of the propeller 14 is a nucleating zone 18 used to form the ice nuclei. The zone 18 comprises a feed conduit 20 for the introduction of a moist air stream and a diaphragm 22 to provide for the introduction of propane, or similar gas, into the moist air stream. The conduit 20 passes through the housing and as shown is L-shaped. The diaphragm 22 is disposed in the discharge end of the conduit 20 and further is connected to a conduit 24 which passes through the housing 12. In communication with the conduit 20 is a feed line 26 to bleed water into the air stream.

Located downstream of the propeller 14 or on the high pressure side and axially spaced apart from and generally axially aligned with the nucleating zone 18 is a nozzle 28 which faces into the direction of the flow of air created by the propeller 14. The nozzle is connected to a water supply by conduit 30 which passes through the housing 12. Water flowing through the conduit 30 and the nozzle 28 is broken up into droplets.

In the operation of the snow precipitator, the propeller 14 is actuated by a motor or other means (not shown) to move ambient air at less than 0C, and at atmospheric humidity through the housing. Compressed air at any humidity, including a high humidity, and at a convenient pressure, say 10 to 15 psi in introduced into conduit 20. Water at a rate determined by the relative humidity of the atmosphere but typically perhaps of from 0.1 quarts to 20 quarts/minute is bled into the compressed air through feed line 26. Liquid propane at a rate determined by the desired production rate of snow and typically from about 0.5 to 15 lbs/hour say for example 2 lbs/hour is discharged through the diaphragm 22, which has an orifice of about 0.010 inches, and into the saturated air stream. When discharged into the air stream the propane goes through a phase change into gas and absorbs heat from the air stream. If desired, other expanding gases or refrigerants which have a high heat of vaporization and would lower the temperature of the air stream to below about 40C on expansion or in a phase change may be used. For example, other hydrocarbons like butane, ethane, methane, and other liquified gases such as liquid oxygen, halocarbons like freon, carbon dioxide, etc. may be used, as well as ammonia, and sulfur dioxide. The refrigerant may incur a phase change froma liquid to a gas or may simply be an expanding gas. Other typical refrigerants are set forth in the Handbook of Chemistry and Physics,'47th Edition, Section E, pages 17-25.

The expanding propane cools a portion of the saturated air below -40C and causes the formation of generally uniform ice nuclei by homogeneous nucleation within the air stream. The average particle size of the ice nuclei formed without addition of bleed water is generally between about 0.1 to microns say for example less than one micron and with bleed water may be increased to between about 125 to 250 microns say about 150 microns. The nuclei are then discharged into the air stream.

Water enters the conduit 30 and flows through the nozzle at any temperature in excess of 0C and generally between 1 to C say about 4C at a rate of between 1-300 gallons/minute for example 15 gallons/minute and is forced through the nozzle 28 at any rate to produce the desired particle size between about 40 and 100 psi for example 80 psi. This temperatureis advantageous in that it prevents anchor ice from forming in the conduit 30 and in the nozzle. The nozzle breaks the water into droplets of suitable size say between 100 and 500 microns for example about 200 microns, and they are discharged countercurrent and directly into the flow of air and ice nuclei. The droplets are supercooled to below 0C by the ambient air flowing through the housing.

These supercooled droplets are then infected by col lision with the ice nuclei previously formed which have traveled a short distance say between 2 to 8 inches. When a drop is infected with an ice nuclei, spicules of ice form very rapidly within it, releasing latent heat until the droplet becomes an ice water mixture at a temperature of about 0C remaining at this temperature until the freezing process is completed through the exchange of heat to the surrounding atmosphere. This exchange of heat with the surrounding atmosphere progressively continues both while the droplet is within the precipitator and after the ice crystals are discharged from the end of the housing into the atmosphere where the freezing process is continued until the droplet is all or largely all frozen and the particles fall to the ground as snow.

' rounding air is about three times greater than in concurrent operation, hastening the supercooling process.

Although the nucleating zone 18 has been shown to 'include an L-shaped conduit with the diaphragm located near the discharge end of the conduit carrying the moist air, it is possible for it to take other forms. For example, the moist air may flow through a venturi passage and the refrigerant injected prior to the constriction as shown in FIG. 3 at the constriction or just beyond the constriction. Also the nucleating zone may be of a non-unitary construction and the diaphragm disposed adjacent to the discharge end of the conduit 20.

When compressed air is allowed to expand adiabatically, the temperature of the air falls about 10C for each 8 percent decrease in pressure. Therefore, if the air is initially at a temperature near 0C expansion from a modest pressure of 20lbs/inch is more than sufficient to bring the temperature below C. If the atmospheric air initially has a relative humidity higher than about percent, it will become saturated in the course of this expansion. In thissituation, in the initial instant after the temperature falls below 40C, very large numbers of very small ice nuclei, say for example,

7 in the range of 40 to 60 angstroms form spontaneously.

Accordingly, in FIG. 2, in an alternative embodiment of the invention, the nucleating zone comprises a feed conduit 34 and a nozzle 36 in communication with the conduit 34. The nozzle 36is adapted to release saturated compressed'air through a nozzle to spontane'ousiy form ice nuclei. Also, in this embodiment the flow of air and ice nuclei maybe concurrent with the flow of the drops discharged from the nozzle 36. Again, an efficient economic operation is provided when the formation of ice nuclei and the water drops are separately 1 created and then combined to form the iceinfected droplets.

Our invention has been described in reference to homogeneous nucleation when a refrigerant such as propane or carbon dioxide is injected into a stream of saturated air to lower the temperature to below about 40C to form the ice nuclei as shown in FIG. 1 or when compressed air is cooled by expansion as shown in FIG. 2. It is also within the scope of this invention that heterogeneous or isomorphic nucleation may be used to form the ice nuclei in the nucleating chamber, as for example by the introduction of silver iodide smoke or comminuted natural ice. Referring again to FIG. 1, the saturated air stream flows through the feed conduit 20 at a temperature of less than 0C. A finely foreign nucleating agent such as a solid particle or product like a silver salt such as silver iodide is injected into this air stream such as through line 26. The silver iodide or other nucleating agent initiates the formation of ice crystals in a supercooled saturated air stream. Also, the air stream may be treated with foreign crystalline substances which may normally have a hemimorphic hexagonal crystalline structure similar to that of ice. For example, wurtzite has been found to be satisfactory. Also various natural minerals in a finely divided state may be similarly employed to initiate crystallization in the supercooled air stream; namely, zincite, nephelite, and lead iodide may also be used. If desired, ice nuclei per se may also be injected into the saturated stream. Also, certain resinous compounds, such as urea, have also been effective.

Although our invention has been described in reference to particular embodiments wherein the steps for the formation of ice nuclei and water droplets are controlled separately, it is to be understood that although the embodiments described showed a single nucleating zone and nozzle there may be employed in a particular operation a plurality of nucleating zones and nozzles within a housing and the orifice sizes may vary. Also depending upon the amount of snow to be generated, the flow rates of compressed air, propane, bleed water, ambient air, etc., will vary.

Having described our invention, what we claim is: l. A method for making snow which comprises: i a. disintegrating a water stream to form water droplets at a temperature of greater than 0C in a first zone; I

b. supercooling the droplets so formed to less than 0C by flowing a mass of ambient air about the droplets;

c. forming ice nuclei in a second separate zone independent of the formation of the water droplets; infecting the water droplets with the ice nuclei in a third zone distinct from the first and second zones;

e. discharging the ice-infected water droplets through a large volume of the ambient air; and

f. removing progressively the latent heat of the iceinfected water droplets until the water droplets are more or less substantially completely frozen and in a snow-like state.

2. The method of claim 1 where the ice nuclei are formed by injecting into a separate stream of moist cold air a refrigerant adapted to lower the temperature of the moist stream to less than about 40C whereby the ice nuclei are formed by homogeneous nucleation.

3. The method of claim 2 which includes bleeding water into the moist stream of air and wherein the refrigerant is an expanding gas, and further which includes forming the water droplets in the first zone by flowing the water through a nozzle.

4. The method of claim 1 wherein the ice nuclei are formed by the expansional cooling of saturated compressed air.

5. The method of claim 1 wherein the ice nuclei and the ambient air flow countercurrent to the direction of flow of the water droplets thereby increasing the rate of transfer of the heat from the water drops to the air to 0C b y flowing an air stream about the droplets; c. forming 1ce nuclei;

d. controlling the formation of ice nuclei as a step separate from and independent of the formation of the water droplets;

e. infecting the water droplets with the ice nuclei;

f. discharging the ice-infected water droplets through a large volume of the air stream; and

g. removing progressively the latent heat of the iceinfected water droplets until the water droplets are more or less substantially completely frozen and in a snow-like state. 1

'8. The method of claim 7 wherein the control of the formation of the water droplets and the ice nuclei as separate steps is accomplished by:

disintegrating the water stream to form the water droplets in a first zone; and

controlling the formation of the ice nuclei as a separate step in a second zone distinct from the first zone.

9. The method of claim 8 which includes infecting the water droplets with the ice nuclei in a third zone distinct from the first and second zones.

10. The method of claim 8 wherein the controlled formation of the ice nuclei is accomplished by injecting into a separate stream of moist cold air a refrigerant adapted to lower the temperature of the moist stream to less than about 40C whereby the ice nuclei are formed by homogeneous nucleation.

11. The method of claim 10 which includes bleeding water into the moist stream of air and where the refrigerant is an expanding gas.

12. The method of claim 7 which includes controlling the formation of the ice nuclei through expansional cooling of saturated compressed air.

13. The method of claim 7 wherein the ice nuclei and air stream flow countercurrent to the direction of the water droplets thereby increasing the rate of transfer of heat from the water droplets to the air to provide increased supercooling.

14. The method of claim 7 wherein the ice nuclei and air stream flow concurrently with the direction of flow of the water droplets. 

1. A method for making snow which comprises: a. disintegrating a water stream to form water droplets at a temperature of greater than 0*C in a first zone; b. supercooling the droplets so formed to less than 0*C by flowing a mass of ambient air about the droplets; c. forming ice nuclei in a second separate zone independent of the formation of the water droplets; d. infecting the water droplets with the ice nuclei in a third zone distinct from the first and second zones; e. discharging the ice-infected water droplets through a large volume of the ambient air; and f. removing progressively the latent heat of the ice-infected water droplets until the water droplets are more or less substantially completely frozen and in a snow-like state.
 2. The method of claim 1 where the ice nuclei are formed by injecting into a separate stream of moist cold air a refrigerant adapted to lower the temperature of the moist stream to less than about -40*C whereby the ice nuclei are formed by homogeneous nucleation.
 3. The method of claim 2 which includes bleeding water into the moist stream of air and wherein the refrigerant is an expanding gas, and further which includes forming the water droplets in the first zone by flowing the water through a nozzle.
 4. The method of claim 1 wherein the ice nuclei are formed by the expansional cooling of saturated compressed air.
 5. The method of claim 1 wherein the ice nuclei and the ambient air flow countercurrent to the direction of flow of the water droplets thereby increasing the rate of transfer of the heat from the water drops to the air to provide increased supercooling.
 6. The method of claim 1 wherein the size of the ice nuclei are between about 0.1 to 1 microns and the size of the water droplets are between 100 to 500 microns and further where the water droplets are initially disintegrated at a temperature of about 4*C and supercooled to less than 0*C.
 7. A method for making snow which comprises: a. disintegrating a water stream to form water droplets at a temperature of greater than 0*C; b. supercooling the droplets so formed to less than 0*C by flowing an air stream about the droplets; c. forming ice nuclei; d. controlling the formation of ice nuclei as a step separate from and independent of the formation of the water droplets; e. infecting the water droplets with the ice nuclei; f. discharging the ice-infected water droplets through a large volume of the air stream; and g. removing progressively the latent heat of the ice-infected water droplets until the water droplets are more or less substantially completely frozen and in a snow-like state.
 8. The method of claim 7 wherein the control of the formation of the water droplets and the ice nuclei as separate steps is accomplished by: disintegrating the water stream to form the water droplets in a first zone; and controlling the formation of the ice nuclei as a separate step in a second zone distinct from the first zone.
 9. The method of claim 8 which includes infecting the water droplets with the ice nuclei in a third zone distinct from the first and second zones.
 10. The method of claim 8 wherein the controlled formation of the ice nuclei is accomplished by injecting into a separate stream of moist cold air a refrigerant adapted to lower the temperature of the moist stream to less than about -40*C whereby the ice nuclei are formed by homogeneous nucleation.
 11. The method of claim 10 which includes bleeding water into the moist stream of air and where the refrigerant is an expanding gas.
 12. The method of claim 7 which includes controlling the formation of the ice nuclei through expansional coolIng of saturated compressed air.
 13. The method of claim 7 wherein the ice nuclei and air stream flow countercurrent to the direction of the water droplets thereby increasing the rate of transfer of heat from the water droplets to the air to provide increased supercooling.
 14. The method of claim 7 wherein the ice nuclei and air stream flow concurrently with the direction of flow of the water droplets. 